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dc.contributor.authorEngmann, Sarah
dc.contributor.authorStano, Michal
dc.contributor.authorPapp, Peter
dc.contributor.authorBrunger, Michael James
dc.contributor.authorMatejcik, Stefan
dc.contributor.authorIngolfsson, Oddur
dc.date.accessioned2013-02-12T03:21:51Z
dc.date.available2013-02-12T03:21:51Z
dc.date.issued2013-01-24
dc.identifier.citationEngmann, S., Stano, M., Papp, P., Brunger, M.J., Matejcik, S. and Ingolfsson, O., 2013. Absolute cross sections for dissociative electron attachment and dissociative ionization of cobalt tricarbonyl nitrosyl in the energy range from 0 eV to 140 eV. Journal of Chemical Physics, 138, 044305.en
dc.identifier.issn0021-9606
dc.identifier.urihttp://hdl.handle.net/2328/26631
dc.description.abstractWe report absolute dissociative electron attachment (DEA) and dissociative ionization (DI) cross sections for electron scattering from the focused electron beam induced deposition (FEBID) precursor Co(CO)3NO in the incident electron energy range from 0 to 140 eV. We find that DEA leads mainly to single carbonyl loss with a maximum cross section of 4.1 × 10−16 cm2, while fragmentation through DI results mainly in the formation of the bare metal cation Co+ with a maximum cross section close to 4.6 × 10−16 cm2 at 70 eV. Though DEA proceeds in a narrow incident electron energy range, this energy range is found to overlap significantly with the expected energy distribution of secondary electrons (SEs) produced in FEBID. The DI process, on the other hand, is operative over a much wider energy range, but the overlap with the expected SE energy distribution, though significant, is found to be mainly in the threshold region of the individual DI processes.en
dc.language.isoen
dc.publisherAmerican Institute of Physicsen
dc.subjectPhysicsen
dc.subjectElectron impact ionisationen
dc.subjectOrganic compoundsen
dc.subjectDissociationen
dc.titleAbsolute cross sections for dissociative electron attachment and dissociative ionization of cobalt tricarbonyl nitrosyl in the energy range from 0 eV to 140 eVen
dc.typeArticleen
dc.rights.licenseIn Copyright
local.contributor.authorOrcidLookupBrunger, Michael James: https://orcid.org/0000-0002-7743-2990en_US


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