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The toluene-Ar complex: S0 and S1 van der Waals modes, changes to methyl rotation, and torsion-van der Waals vibration coupling
(American Institute of Physics, 2013-02-25)
The methyl rotor and van der Waals vibrational levels in the S1 and S0 states of toluene-Ar have been investigated by the technique of two-dimensional laser induced fluorescence (2D-LIF). The S0 van der Waals and methyl ...
Methyl rotor dependent vibrational interactions in toluene
(American Institute of Physics, 2013-04-02)
The methyl rotor dependence of a three state Fermi resonance in S1 toluene at ∼460 cm−1 has been investigated using two-dimensional laser induced fluorescence. An earlier time-resolved study has shown the Fermi resonance ...